Evaluation of internal morphology and engineering properties of graphite-filled UHMWPE nanocomposites produced using a novel octa-screw kneading extruder

Ultra-high molecular weight polyethylene (UHMWPE) is a very attractive polymer employed as a high performance material, while filler-reinforced composites have demonstrated its feasibility in various applications. Melt-mixing in an extruder is a key process in the development of polymer nanocomposit...

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Bibliographic Details
Published inJournal of polymer engineering Vol. 39; no. 3; pp. 264 - 270
Main Authors Liu, Cheng-Ying, Ishigami, Akira, Kurose, Takashi, Ito, Hiroshi
Format Journal Article
LanguageEnglish
Published De Gruyter 01.03.2019
Subjects
composites
graphite
octa-screw extruder
UHMWPE
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Summary:Ultra-high molecular weight polyethylene (UHMWPE) is a very attractive polymer employed as a high performance material, while filler-reinforced composites have demonstrated its feasibility in various applications. Melt-mixing in an extruder is a key process in the development of polymer nanocomposites. Due to its high melt viscosity, dispersion of fillers is considered as a challenge in UHMWPE nanocomposites preparation process. In this work, we have prepared graphite-filled UHMWPE nanocomposites using a novel octa-screw melt kneading extruder. The engineering properties as well as the morphology of kneaded nanocomposites were characterized using tensile tester, friction and wear tester, scanning electron microscopy, optical profilemeter, polarized optical microscope, thermogravimetric analysis, differential scanning calorimetry, etc. The experimental results suggested good dispersion of graphite in the UHMWPE nanocomposites, demonstrating the excellent capability of the octa-screw extruder in compounding the graphite-filled nanocomposites. The yield strengths of the nanocomposites increase by 10% (from 21.6 MPa to 23.8 MPa) with the addition of 2% graphite. When the filler percentage was increased to 20%, the yield strengths improved from 21.6 to 27.4 MPa (an increase of 26.8%) for the graphite-filled composites. Furthermore, the crystallinity of UHMWPE nanocomposites increased with the content of graphite fillers, while the pyrolysis temperature of the composites increased with the content of graphite fillers.
ISSN:0334-6447
2191-0340
DOI:10.1515/polyeng-2018-0288