Mangrove tannins and their flavanoid monomers as alternative steel corrosion inhibitors in acidic medium

• Published in: Corrosion science Vol. 49; no. 2; pp. 402 - 417
• Main Authors: Rahim, Afidah A., Rocca, E., Steinmetz, J., Kassim, M.J., Adnan, R., Sani Ibrahim, M.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.02.2007; Elsevier Science
• Subjects: Applied sciences; Corrosion; Corrosion environments; Corrosion prevention; Exact sciences and technology; F. Flavanoids; I. Inhibition efficiency; M. Molecular modelling; Metals. Metallurgy; T. Tannin; I. Inhibition efficiency; F. Flavanoids; T. Tannin; M. Molecular modelling; Corrosion; Efficiency; Corrosion protection; Acid medium; Modeling; Corrosion inhibitor
• ISSN: 0010-938X; 1879-0496
• DOI: 10.1016/j.corsci.2006.04.013

The inhibitive behaviour on steel of flavanoid monomers that constitute mangrove tannins namely catechin, epicatechin, epigallocatechin and epicatechingallate was investigated in an aerated HCl solution via electrochemical methods. The monomers were found to be mainly cathodic inhibitors and the inhibition efficiency was dependent on concentration. To explain the adsorptive behaviour of the molecules on the steel surface, a semiempirical approach involving quantum chemical calculations using HyperChem 6.0 was undertaken. The HOMO electronic density of the molecule was used to explain the inhibiting mechanism. The most probable adsorption centers were found in the vicinity of the phenolic groups. In a second part, the use of mangrove tannin, extracted from the mangrove barks as steel corrosion inhibitors in acidic media was investigated and its inhibitive efficiency was compared with that of commercial mimosa, quebracho and chestnut tannins. The inhibitive performance of mangrove tannins was comparable to the other tannins investigated, indicating their potential in corrosion protection.