Microwave catalytic conversion of acetylene for co-production of hydrogen and carbon nanotubes

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 454; no. P1; p. 140115
• Main Authors: Balyan, Sonit, Jiang, Changle, Caiola, Ashley, Hu, Jianli
• Format: Journal Article
• Language: English
• Published: Switzerland Elsevier B.V 15.02.2023; Elsevier
• Subjects: Acetylene; Carbon nanotubes; Heterogeneous catalysis; Hydrogen production; Microwave heating; Carbon nanotubes; Heterogeneous catalysis; Microwave heating; Hydrogen production; Acetylene
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2022.140115

•Integration of MW-plasma and MW-irradiation into single modular reactor.•Microwave irradiation for catalytic acetylene decomposition has never been reported.•Microwave irradiation outperforms conventional heating during C2H2 pyrolysis.•Decomposition temperature of C2H2 to crystalline carbon decreases to 350 °C using MW.•Developed Ni and Ni-Pd based CNT and Al2O3 supported catalysts. Natural gas conversion to hydrogen and solid carbon can drastically reduce the carbon footprint. Microwave plasma pyrolysis is an emerging process for chemical industries to directly convert methane (CH4), the major component of natural gas, to hydrogen and carbon, which offers benefits such as fast process dynamics, flexibility, and high product yield. However, the formation of unwanted by-products, like acetylene (C2H2), will require extra cost for gas separation. Plasma pyrolysis of CH4 produces large amount of acetylene at downstream, which is currently used mainly for welding. To avoid gas separation and upgrade acetylene from the downstream of methane plasma reactor, a novel approach toward its transformation to carbon nanotubes (CNT) and pure hydrogen (H2) over Ni-based bimetallic catalyst driven by microwave irradiation has been reported in this work. The dominant gas product was hydrogen. Low concentrations of methane, ethane, and ethylene were observed in the product stream. Catalytic acetylene decomposition was carried out at 400 °C over Al2O3 supported Ni catalyst. The results showed that, at 400 °C, acetylene was dehydrogenated to CNT and hydrogen was the dominant gas in product stream over 10Ni-1Pd-Al2O3 catalyst. Characterizations of spent catalysts was conducted using Raman spectroscopy and transmission electron microscopy (TEM) to investigate the properties of carbon deposited over the catalyst during the catalytic acetylene decomposition. The results highlight that methane can be efficiently converted to hydrogen and CNT through 2-step process, microwave plasma and microwave catalytic conversion of intermediate acetylene, operated in a single reactor system driven by microwave.