Regioselective indium(III) trifluoromethanesulfonate-catalyzed hydrothiolation of non-activated olefins

Indium(III) trifluoromethanesulfonate was found to be an excellent catalyst for the highly regioselective intra- and intermolecular addition of thiols to non-activated olefins and could be recycled and reused without loss of activity.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 3; pp. 332 - 334
Main Authors Weiwer, M, Coulombel, L, Dunach, E
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.01.2006
Subjects
Alkenes - chemistry
Catalysis
Cations
Chemistry
Chemistry, Multidisciplinary
Cyclization
Indium - chemistry
Mesylates - chemistry
Models, Chemical
Molecular Structure
Organometallic Compounds - chemistry
Physical Sciences
Science & Technology
Sulfhydryl Compounds - chemistry
UNSATURATED-COMPOUNDS
TRIFLATE
MILD
THIOLS
DIELS-ALDER REACTIONS
ACIDS
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Summary:Indium(III) trifluoromethanesulfonate was found to be an excellent catalyst for the highly regioselective intra- and intermolecular addition of thiols to non-activated olefins and could be recycled and reused without loss of activity.
ISSN:1359-7345
1364-548X
DOI:10.1039/b513946e