Chemistry and stability of precipitates from aqueous solutions of 2,4,6-trimercaptotriazine, trisodium salt, nonahydrate (TMT-55) and mercury (II) chloride

• Published in: Water research (Oxford) Vol. 34; no. 11; pp. 3005 - 3013
• Main Authors: Henke, Kevin R, Robertson, David, Krepps, Matthew K, Atwood, David A
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.08.2000; Elsevier Science
• Subjects: Applied sciences; chemical precipitation; Exact sciences and technology; Industrial wastewaters; mercury; Pollution; TMT-55; trimercaptotriazine; Wastewaters; water treatment; Water treatment and pollution; TMT-55; water treatment; trimercaptotriazine; chemical precipitation; mercury; Chemical precipitation; Industrial waste water; Mercury II Chlorides; Triazine derivatives; Physicochemical purification; Waste water purification; Experimental study; Organic compounds; Hydrates; Heavy metal
• ISSN: 0043-1354; 1879-2448
• DOI: 10.1016/S0043-1354(00)00038-5

2,4,6-trimercaptotriazine, trisodium salt, nonahydrate (TMT-55) is a planar C 3 symmetric compound that is used commercially to precipitate mercury and other heavy metals from waste waters and contaminated natural waters. A series of laboratory experiments and analyses were performed to evaluate the chemistry and stability of mercury trimercaptotriazine “Hg-TMT” precipitates that result from the addition of aqueous solutions of TMT-55 to aqueous solutions of mercury(II) chloride (HgCl 2). Several Hg-TMT species exist, most of which were previously unrecognized. The leaching properties, chemistry and long-term stability of the solids are very diverse. As examples, the white and yellow varieties of Hg-TMT are often unstable in both water and air, and may release more than 6000  μg/l of mercury into distilled and deionized water leachates. Although waste waters and contaminated ground waters are likely to contain less mercury than the HgCl 2 solutions used in this study, individuals should recognize that any Hg-TMT compounds are likely to be chemically complex and perhaps unstable under aqueous or atmospheric conditions.