Synthesis of highly reactive organosulfur compounds

Application of novel bowl‐type and dendrimer‐type steric protection groups to the first synthesis of stable aromatic S‐nitrosothiols is described. These compounds showed remarkable thermal stability whereas they easily reacted with appropriate reagents. X‐ray crystallographic analysis established th...

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Bibliographic Details
Published inHeteroatom chemistry Vol. 13; no. 5; pp. 414 - 418
Main Authors Okazaki, Renji, Goto, Kei
Format Journal Article
LanguageEnglish
Published New York Wiley Subscription Services, Inc., A Wiley Company 2002
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Summary:Application of novel bowl‐type and dendrimer‐type steric protection groups to the first synthesis of stable aromatic S‐nitrosothiols is described. These compounds showed remarkable thermal stability whereas they easily reacted with appropriate reagents. X‐ray crystallographic analysis established their structures, where the CSNO linkage adopts only the syn conformation. Synthesis of a stable sulfenic acid by taking advantage of the bowl‐type substituent is also delineated. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:414–418, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10068
Bibliography:ark:/67375/WNG-FF9RPH8L-Z
ArticleID:HC10068
istex:AC9BE35CD6F640D6DF00BD5518F0C4B6B50C5F8B
Ministry of Education, Culture, Sports, Science and Technology, Japan
ISSN:1042-7163
1098-1071
DOI:10.1002/hc.10068