Syntheses, Crystal Structures, and Luminescence Properties of Dinuclear Metal (Ag+ and Cu+) Complexes with the Ligand 2-MTPP [2-MTPP = 2-(Methylthio)-4-(pyridin-2-yl)pyrimidine]

Reactions of the ligand 2‐MTPP [2‐MTPP = 2‐(methylthio)‐4‐(pyridin‐2‐yl)pyrimidine] with AgNO3 and CuI produced dinuclear silver(I) (1) and copper(I) (2) complexes, respectively. Both complexes adopt a chair‐like structure in which two 2‐MTPP ligands and two metal ions are joined together through M–...

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Published inZAAC - Journal of Inorganic and General Chemistry Vol. 637; no. 10; pp. 1423 - 1426
Main Authors Zhu, Hai-Bin, Zhang, Shu-Ying, Lu, Xin, Yang, Wen-Na, Gou, Shao-Hua, Chen, Jing
Format Book Review Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.08.2011
WILEY‐VCH Verlag
Subjects
Copper
Crystal structure
Luminescence
Silver
Thioethers
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Summary:Reactions of the ligand 2‐MTPP [2‐MTPP = 2‐(methylthio)‐4‐(pyridin‐2‐yl)pyrimidine] with AgNO3 and CuI produced dinuclear silver(I) (1) and copper(I) (2) complexes, respectively. Both complexes adopt a chair‐like structure in which two 2‐MTPP ligands and two metal ions are joined together through M–N and M–S coordination bonds. The luminescence properties of both complexes were investigated in solid state at room temperature.
Bibliography:National Natural Science Foundation of China - No. 20801011
ark:/67375/WNG-1KTZDB2F-2
Teaching and Research Program for the Excellent Young Teachers of Southeast University - No. 3207041202
ArticleID:ZAAC201100124
istex:D0B1F39D7512B7499389632C3BDD9AEAA78F209C
Supporting information for this article is available on the WWW under http://dx.doi.org/10.1002/zaac.201100124 or from the author.
Supporting information for this article is available on the WWW under
or from the author.
http://dx.doi.org/10.1002/zaac.201100124
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.201100124