Synthesis and Characterization of Silica Core/Multilayered Cobalt Ferrite-Silica Shell Particles for Lipase Immobilization
Multilayered core/shell particles were prepared by four-step deposition of cobalt ferrite layers and then deposition of external silica layer on the surface of silica core particles. The ferrite nanoparticles were obtained by co-precipitation of Co2+ and Fe3+ ions at pH=11 and pH=15, respectively. T...
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Published in | Materials research (São Carlos, São Paulo, Brazil) Vol. 24; no. 6; p. 1 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English Portuguese |
Published |
Sao Carlos
Universidade Federal do Sao Carlos, Departamento de Engenharia de Materiais
01.01.2021
ABM, ABC, ABPol Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) |
Subjects | |
Online Access | Get full text |
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Summary: | Multilayered core/shell particles were prepared by four-step deposition of cobalt ferrite layers and then deposition of external silica layer on the surface of silica core particles. The ferrite nanoparticles were obtained by co-precipitation of Co2+ and Fe3+ ions at pH=11 and pH=15, respectively. The agglomerated silica core/cobalt ferrite shell particles were obtained at extremely basic pH (pH=15), while at pH =11, monodispersed and non-aggregated core-shell particles were obtained. The poly(diallyldimethylammonium chloride)-functionalized silica core/ferrite shell particles were used as templates for deposition of mesoporous silica layers (obtained by neutralization of highly basic sodium silicate solution). The obtained porous multilayered core/shell particles were used as a host for covalent lipase immobilization inside the external silica layer. The initial activity of immobilized enzymes was about 13-fold lower than the native one, however, it showed good reusability and improved thermal stability compared to native ones. |
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ISSN: | 1516-1439 1980-5373 1980-5373 |
DOI: | 10.1590/1980-5373-mr-2021-0130 |