Adsorption behavior of silver quantum dots by a novel super magnetic CoFe2O4-biochar-polymeric nanocomposite

• Published in: Journal of colloid and interface science Vol. 606; no. Pt 2; pp. 1597 - 1608
• Main Authors: Mahmoud, Mohamed E., Abouelanwar, Magda E., Mahmoud, Safe ELdeen M.E., Abdel Salam, Mohamed
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 15.01.2022
• Subjects: adsorption; Ag-QDs; Biochar; Citrus reticulata; Citrus sinensis; Coagulative removal study; cobalt; CoFe2O4; crosslinking; ferrimagnetic materials; industrialization; magnetism; microwave radiation; nanocomposites; pollutants; pollution; polymers; Polyurea formaldehyde polymer; silver; sorption isotherms; wastewater; CoFe2O4; Coagulative removal study; Biochar; Ag-QDs; Polyurea formaldehyde polymer
• ISSN: 0021-9797; 1095-7103; 1095-7103
• DOI: 10.1016/j.jcis.2021.08.102

[Display omitted] Recent industrial development and research progress in nanotechnology have led to the release of a number of nanomaterials with particle sizes (1–10 nm) which are categorized as quantum dots (QDs) in aquatic system. Disposal away of such QDs will cause potential pollution to the environment. Therefore, removal of disposed QDs from wastewater represents a challenging research subject for scientists and engineers. Hence, the objective of this study is devoted to assess the process of coagulative removal of silver quantum dots (Ag-QDs), as an example, from water by a novel super magnetic nanocomposite. Such material was aimed to prepare from the chemical combination and reaction of a generated Citrus sinensis and Citrus reticulata peels biochar (SMCsr-B) with spinel cobalt ferrite (CoFe2O4) as a super-magnetic source. The produced (SMCsr-B) was then crosslinked with polyurea-formaldehyde polymer (PUF) using EDA in only two minutes via microwave irradiation to produce (SMCsr-B/PUF). The SEM, EDX, FT-IR, XRD, and XPS analyses of the assembled (SMCsr-B/PUF) nanocomposite were acquired to confirm surface morphology and chemical structure. Controlling experimental factors were investigated as pH, time, and Ag-QDs pollutant concentration using microwave irradiative removal technique to establish the efficiency of coagulative adsorption of Ag-QDs onto (SMCsr-B/PUF). The solution (pH 5) was proved to exhibit the higher removal percentages of Ag-QDs in 15–25 s. SMCsr-B/PUF nanocomposite exhibited high removal efficiency as 93.12%, 92.39% and 92.48% upon using 20, 40 and 60 mg L−1 of Ag-QDs, respectively in presence of 10 mM NaCl. The kinetic and equilibrium adsorption data were best fitted to Freundlich model. The prepared SMCsr-B/PUF was successfully utilized as an efficient super magnetic nanocomposite for removal and recovery of Ag-QDs from aqueous environment.