Water-based Processing of Fiberboard of Acrylic Resin Composites Reinforced with Cellulose Wood Pulp and Cellulose Nanofibrils
Despite the great potential of cellulose wood pulp and cellulose nanofibrils as reinforcing filler in thermoplastics, its use is limited due to its tendency to form agglomerates and due to its high hydrophilic character. Here we describe fiberboard composites with high contents of wood pulp or cellu...
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Published in | Journal of renewable materials Vol. 7; no. 5; pp. 403 - 413 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Henderson
Tech Science Press
2019
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Subjects | |
Online Access | Get full text |
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Summary: | Despite the great potential of cellulose wood pulp and cellulose nanofibrils as reinforcing filler in thermoplastics, its use is limited due to its tendency to form agglomerates and due to its high hydrophilic character. Here we describe fiberboard composites with high contents of wood
pulp or cellulose nanofibrils, and a resin of poly (styrene-methyl-methacrylate-acrylic acid) used as water-based emulsion. Cellulose wood pulp and cellulose nanofibrils were used directly in the form of water suspensions. The method is based on the flocculation of the polymer emulsion followed
by agglomeration of a mixture of the polymer emulsion and cellulose suspension, leading to the co-precipitation of the composite material, which can be easily separated from the water phase. Composites with acrylic polymer/cellulose fibers in the proportions of 75:25, 50:50 and 25:75 wt% were
prepared. Composites were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and water absorption tests. SEM analysis revealed a very good dispersion of the fibers without
evidence of agglomeration, which led to superior mechanical properties. These results showed the effectiveness of the methodology and the potential of cellulose wood pulp and CNF as reinforcement fillers in fiberboard composites and any other high fiber-content materials. |
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Bibliography: | 2164-6325(20190515)7:5L.403;1- |
ISSN: | 2164-6325 2164-6341 2164-6341 |
DOI: | 10.32604/jrm.2019.01846 |