Surface analysis of different boundary layers on steel discs formed in a lubricated tribocontact during laboratory test compared with field application

• Published in: Analytical and bioanalytical chemistry Vol. 390; no. 6; pp. 1527 - 1535
• Main Authors: Stadler, Astrid, Brenner, Josef, Pauschitz, Andreas, Wendrinsky, Josef, Schindel, Andreas, Nauer, Gerhard E
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Berlin/Heidelberg : Springer-Verlag 01.03.2008; Springer-Verlag
• Subjects: additives; Analytical Chemistry; Biochemistry; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Food Science; Laboratory Medicine; Lubricated tribo-contact; Monitoring/Environmental Analysis; Original Paper; Surface analysis; Tribo-layer; Tribology; Additives; Surface analysis; Lubricated tribo-contact; Tribo-layer; Tribology
• ISSN: 1618-2642; 1618-2650
• DOI: 10.1007/s00216-007-1730-0

The aim of this study was to gain knowledge of tribological layers on a steel disc. This steel disc has been used in a transmission system in the field. ATF-oil (automatic transmission fluid), which contains different surface-adhering additives, serves as a lubricant and as a cooling fluid in the tribological system. Over time, the tribological characteristics of the system changed. Special interest in this study lies in the modifications of the steel surface. The field-used disc was therefore compared with model tested discs. In a disc-on-disc tribometer, all samples are tested for a short period of time to evaluate the actual condition of the system regarding friction behaviour. Analysis and characterisation of surfaces and layer formation were carried out with, among other techniques, 3D topography, SEM / EDX, AFM, XPS, and ToF-SIMS. Results indicate that in some regions a complex composed tribological layer is formed. Differences were detected between the steel discs used in the field and the model discs. This indicates the problem of evaluation of long-term behaviour exclusively by use of short or accelerated model experiments. A combination of carefully selected and sophisticated analytical methods is necessary to trace small changes of the system. [graphic removed]