Chemical, thermal and rheological characteristics of composite polymerized asphalts

• Published in: Fuel (Guildford) Vol. 227; pp. 289 - 299
• Main Authors: Wang, Jiayu, Yuan, Jie, Kim, Kwang W., Xiao, Feipeng
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.09.2018; Elsevier BV
• Subjects: Addition polymerization; Aging; Anti-rutting agent (ARA); Aromatic hydrocarbons; Asphalt; Binders; Carbonyls; Chemical composition; Chemical functional group; Chemical properties; Composite materials; Copolymers; Correlation analysis; Degradation; Functional groups; Large molecular size; Low frequencies; Organic chemistry; Oxidation; Phase shift; Polyethylene; Polyethylenes; Polyethylenes (PE); Polymerization; Rheological properties; Shear modulus; Thermodynamic properties; Viscoelastic master curve; Viscoelasticity; Wavelengths; Polyethylenes (PE); Viscoelastic master curve; Chemical functional group; Correlation analysis; Anti-rutting agent (ARA); Large molecular size
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2018.04.100

[Display omitted] Thermal oxidation has a significant effect on rheological and chemical properties of composite polymerized asphalt. In this study, polyethylenes (PE) and a multi-polymer (a type of anti-rutting agent) were incorporated into asphalt binders at four contents and the properties of polymer-asphalt composite systems were investigated through chemical functional group, molecular size, thermal behavior and rheological characteristics. Due to the formation of large conjugate structure by thermal oxidation, the carbonyl peak shifted to a lower wavenumber after a long-term aging procedure and the aging procedure increased the values of large molecular sizes. However, the degradation of PE played a dominant role during oxidation progress, which significantly decreased the LMS value of composite binders. Therefore the aging process changed the chemical compositions and element component distribution of binders and these changes were influenced by both binder source and polymer contents. In addition, with the increase of polymer modification, the penetration value and phase angle value at low frequency decreased; the endothermic peak area, softening point as well as complex shear modulus at low frequency increased. Therefore, the polymer degradation and polycyclic aromatic hydrocarbon formation should be considered during the aging process, which influenced the rheological performance of composite polymerized asphalts together. Furthermore, the correlation analysis showed that the carbonyl structure index ICdbndO has significant correlations with the difference between glassy modulus and equilibrium modulus, and phase angle master curve plateau δP, the LMS value has significant relationships with phase angle master curve factors δL and δP + δL at a low frequency.