Design of competition nanoreactor with shell-isolated colloidal plasmonic nanomaterials for quantitative sensor platform

• Published in: Talanta (Oxford) Vol. 265; p. 124861
• Main Authors: Guo, Zhi-Yong, Zhang, Chen, Chen, Lin-min, Zeng, Mei-huang, Yao, Qiu-hong, Ye, Ting-Xiu, Luo, He-zhou, Chen, Xiao-mei, Chen, Xi
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.12.2023
• Subjects: Glucose; hell-isolated; Nanoreactor; SERS; hell-isolated; Glucose; SERS; Nanoreactor
• ISSN: 0039-9140; 1873-3573
• DOI: 10.1016/j.talanta.2023.124861

Shell-isolated colloid plasmonic nanomaterials-based nanoreactor is a well-established platform widely applied in catalyst or Surface Enhanced Raman Scattering (SERS) sensors. The potentials versatility of nanoreactor platform is mainly implemented by the well-defined and tailorable structure of colloid plasmonic nanomaterials. Currently, a competitive conjugative-mediated nanoreactor is introduced to determine glucose with SERS. Glucose-conjugating nanoreactor, as convertors of the sensors, are constructed by coordinated deposition colloidal gold nanoparticles with sodium nitroprusside framework (Au@SNF) and covalently bonded 4-mercaptopyridine (4-Mpy) with self-assembly strategy. The nanoreactor contained the signal-amplifier Au@SNF NPs, conjugative-mediated signal receiver 4-Mpy, and signal internal standard molecular CN−. In addition to well-defined morphology and functionality, conjugative-mediated and internal standards method are also employed to benefit the nanoreactor. The two-parameter strategy significantly improves the signal indication and correction. Using this proposed platform, the competitive-mediated nanoreactor provides a quantitative SERS detection of glucose, and extends the applicability of SERS in more complicated and reproducibility analysis. Meanwhile, the nanoreactor based sensors also exhibited better properties to detect glucose in various food samples and bio-samples which provided strongly appliance for glucose sensors. [Display omitted] •Currently, a competitive conjugative-mediated nanoreactor with signal-amplifier Au@SNF NPs, signal receiver 4-Mpy and internal standard molecular CN− is introduced to determine glucose with SERS.•The two-parameter strategy significantly improves the signal indication and correction. The proposed platform extends the applicability of SERS in more complicated and reproducibility analysis.