Molecular Signal Transduction through Conformational Transmission of a Perhydroanthracene Transducer

A biconformational perhydroanthracene 1 was used as a signal transducer. Upon binding of a zinc(II) ion at the bipyridine receptor site, a fluorescence signal is generated at the pyrene effector site.

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 39; no. 10; pp. 1835 - 1837
Main Authors Krauss, Rolf, Weinig, Hans-Georg, Seydack, Matthias, Bendig, Jürgen, Koert, Ulrich
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 15.05.2000
WILEY‐VCH Verlag GmbH
Wiley
Subjects
Chemistry
Chemistry, Multidisciplinary
conformational analysis
fluorescence
molecular switches
Physical Sciences
polycycles
Science & Technology
signal transduction
fluorescence
signal transduction
SWITCH
conformational analysis
molecular switches
STEREOSELECTIVE SYNTHESIS
polycycles
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Summary:A biconformational perhydroanthracene 1 was used as a signal transducer. Upon binding of a zinc(II) ion at the bipyridine receptor site, a fluorescence signal is generated at the pyrene effector site.
Bibliography:istex:478752CDD9A2F7AAA96AD7795FBA273A97C9C7AA
ArticleID:ANIE1835
ark:/67375/WNG-RFS3CC2Q-D
This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. Support by the NMR group of Dr. C. Mügge is gratefully acknowledged.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(20000515)39:10<1835::AID-ANIE1835>3.0.CO;2-S