A Circular Economy Virtuous Example—Use of a Stabilized Waste Material Instead of Calcite to Produce Sustainable Composites

• Published in: Applied sciences Vol. 10; no. 3; p. 754
• Main Authors: Assi, Ahmad, Bilo, Fabjola, Zanoletti, Alessandra, Ducoli, Serena, Ramorino, Giorgio, Gobetti, Anna, Zacco, Annalisa, Federici, Stefania, Depero, Laura E., Bontempi, Elza
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.02.2020
• Subjects: Bottom ash; By products; Calcite; Calcium carbonate; Circular economy; Coal; Composite materials; Economics; Epoxy resins; filler; Fillers; Flue gas; Fly ash; Gases; Incineration; Industrial plant emissions; Mechanical properties; Modulus of rupture in bending; Municipal solid waste; municipal solid waste incineration; Municipal waste management; Natural resources; new composites; Pollutants; Power plants; Solid waste management; Stabilization; Technology assessment; three point bending test; Waste disposal; Waste materials; Waste treatment; Italy
• ISSN: 2076-3417; 2076-3417
• DOI: 10.3390/app10030754

This work reports and analyzes the mechanical properties of some composites obtained using stabilized waste with epoxy resins E-227. For comparison, correspondent composite samples were realized using calcite as a filler. The recovered stabilized waste was obtained by means of a new method to stabilize municipal solid waste incineration (MSWI) fly ash (FA), based on the use of bottom ash (BA). The aim of this paper is to show that the stabilization process, which can be considered a zero—waste treatment, produces inert materials, that can be reused as a filler. The production of new filler was made on a pilot plant, designed to verify the transferability of the proposed stabilization technology. Mechanical analysis revealed that flexural modulus raises by increasing the filler content around 30% wt, independently of filler type, stabilized sample or calcium carbonate. Mechanical properties are lower in the samples with the high amount of filler due to the crowding effect. The morphology of composite materials showed a non-homogeneous dispersion of particles in stabilized sample filler, characterized by large particle agglomerates. Finally, according to the ESCAPE simplified method, the obtained composites result more sustainable in comparison with the corresponding ones produced by using natural resources (like calcite). These findings open new possibilities for the reuse of the stabilized material, in frame of circular economy principles, with environmental and economic advantages.