Entropy and enthalpy change in hydrated ion clusters

A new electrothermodynamic theory was recently developed by (Suck) Salk to treat the hydration of ions suspended in a gas containing water vapor. This theory was successfully applied to a study of the free energy of formation of both positive and negative ions and to an analysis of ion mobility data...

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Bibliographic Details
Published inChemical physics Vol. 102; no. 3; pp. 459 - 466
Main Authors Hagen, D.E., Suck Salk, S.H.
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.03.1986
Elsevier
Subjects
Applied sciences
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
General. Theory
Metals and alloys
Mixtures
Other techniques and industries
Thermodynamic properties
Hydrated ion
Ionic cluster
Hydration
Enthalpy
Entropy
Thermodynamic properties
Free energy
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Summary:A new electrothermodynamic theory was recently developed by (Suck) Salk to treat the hydration of ions suspended in a gas containing water vapor. This theory was successfully applied to a study of the free energy of formation of both positive and negative ions and to an analysis of ion mobility data. Here the new theory is used to study entropy and enthalpy for a variety of hydrated ions. The results compare favorably to experiment and are significantly superior to Thomson theory results.
ISSN:0301-0104
DOI:10.1016/0301-0104(86)80016-7