Size-Fractionated Weathering of Olivine, Its CO2-Sequestration Rate, and Ecotoxicological Risk Assessment of Nickel Release

• Published in: Minerals (Basel) Vol. 13; no. 2; p. 235
• Main Authors: Vink, Jos P. M., Knops, Pol
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.02.2023
• Subjects: Atmospheric models; Carbon dioxide; Carbon dioxide removal; Carbon sequestration; climate change; CO2; Dissolution; Dissolving; Emissions; Environmental conditions; Exploitation; Grain size; grain size distribution; Gravel; Ligands; Metals; mineral enhanced weathering; Minerals; Nickel; Olivine; Particle size; Precipitation; Risk assessment; Shrinking core model; Silicates; Toxicity; Weathering
• ISSN: 2075-163X; 2075-163X
• DOI: 10.3390/min13020235

Olivine, one of the most abundant silicates on earth, thermodynamically captures CO2 in relevant amounts during its dissolution. Upscaling the use of this mineral as a replacement for sand or gravel may contribute to reduce concentrations of greenhouse gasses in the atmosphere. However, the reliable quantification of weathering rates and prognoses for effects of various environmental conditions on weathering are lacking. This currently inhibits the monitoring, reporting and verification of CO2 capture and hampers the exploitation of the carbon dioxide removal economy. A mineral dissolution model was developed, and olivine weathering rates were directly coupled to particle sizes of the ground mineral. A particle size-dependent calculation approach, based on the shrinking core model, showed faster weathering rates as compared to a single-size, monodisperse approach. This provided a better underpinning of the prediction of the overall weathering and, consequently, the sequestration rate of CO2. Weathering of olivine releases nickel, which is incorporated in the mineral. The dissolution model was coupled to advanced biotic ligand models (BLM) for nickel in order to assess potential chronic ecotoxicological risks upon release in the environment. Predicted no-effect concentrations for nickel showed that both the release of Mg and the increase of pH following olivine weathering significantly lowers nickel ecotoxicity.