Clay Mineralogy: A Signature of Granitic Geothermal Reservoirs of the Central Upper Rhine Graben

• Published in: Minerals (Basel) Vol. 11; no. 5; p. 479
• Main Authors: Glaas, Carole, Patrier, Patricia, Vidal, Jeanne, Beaufort, Daniel, Genter, Albert
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.05.2021
• Subjects: Basements; Carbonates; Chemical composition; Chlorite; Clay; Clay minerals; Convection; Crystal structure; Crystalline rocks; Crystallinity; Drilling; Fault lines; Fluids; Fracture zones; Fractures; geothermal reservoir; Graben; Granite; hydrothermal alteration; Hydrothermal fields; Illite; illite-rich illite/smectite mixed-layers; Illites; Mineral exploration; Mineralogy; Minerals; Paleozoic; Permeability; Petrography; Petrology; Quartz; Reservoirs; Sedimentary rocks; Smectites; Temperature; Upper Rhine Graben
• ISSN: 2075-163X; 2075-163X
• DOI: 10.3390/min11050479

Clay minerals are the signature of hydrothermal alterations related to fluid circulation in volcanic and crystalline rocks. In the French part of the Upper Rhine Graben, in the deep-seated granites, illitic minerals (illite and I/S mixed layers (ml)) are typical products of the structurally-controlled argillic alteration in the Paleozoic granitic basement. In the new Illkirch geothermal well, GIL-1, drill-cuttings were studied with various petrographic methods to determine the characteristics of illite in paleo- and present-permeable zones, and to compare the alteration mineralogy with that of geothermal Soultz-sous-Forêts and Rittershoffen sites. Alteration petrography, crystal structure as well as the chemical composition of the illitic minerals and the altered bulk rocks were performed all along the well. This complete characterization, combined with geophysical logs and structural results, highlighted that the illitic minerals at Illkirch, Soultz-sous-Forêts, and Rittershoffen are composed of illite and illite-rich illite-smectite mixed layers (I/S ml) (<10% smectite). Two mineralogical assemblages were distinguished: chlorite + illite resulting from the propylitic alteration after the emplacement of the granitic basement under temperatures higher than 350 °C, and illite + I/S ml + carbonates + quartz resulting from the argillic alteration due to fluid circulation in the fractures at temperatures between 130 and 160 °C. Fracture zones are characterized by the occurrence of illitic minerals (illite and I/S ml), and specifically, by higher quantities of I/S ml in present-day permeable zones than in paleo-permeable zones. A conceptual model of the fracture zones at the interface between the overlying sedimentary rocks and the granitic basement is proposed. The present-day permeability distribution is controlled by the fault and fracture network, which consists of sealed zones and unsealed zones. Fluid convection in the URG implies paleo and present fluids circulating in both fractured sedimentary and crystalline reservoirs. Such circulations develop illitic minerals that could be considered as exploration guides for future geothermal sites in the URG. At Illkirch, the repartition of the present-permeable fracture zones (KFZs) in the GIL-1 well indicates that the moderately argillically altered granite distally situated from the Eschau fault is more permeable than the intensely argillically altered granite close to the Eschau fault.