Flexible Quasi-Solid-State Composite Electrolyte of Poly (Propylene Glycol)-co-Pentaerythritol Triacry-Late/Li1.5Al0.5Ge1.5(PO4)3 for High-Performance Lithium-Sulfur Battery

• Published in: Materials Vol. 14; no. 8; p. 1979
• Main Authors: Deng, Zekun, Zheng, Zhenyang, Ruan, Wenhong, Zhang, Mingqiu
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 15.04.2021; MDPI
• Subjects: cycling performance; Electrodes; Electrolytes; Energy storage; Flux density; Li-ion conductivity; Lithium; Lithium ions; Lithium sulfur batteries; lithium sulfur battery; Mechanical properties; Microscopy; Polymers; Polysulfides; polysulfides shuttle effect; Propylene; quasi-solid-state composite electrolyte; Solid electrolytes; Solid state; Solvents; Sulfur content; Thermogravimetric analysis; United States > US; Germany
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma14081979

With a higher theoretical specific capacity (1675 mAh g−1) and energy density (2600 Wh kg−1), the lithium-sulfur (Li-S) battery is considered as a promising candidate for a next-generation energy storage device. However, the shuttle effect of polysulfides as well as the large interfacial impedance between brittle solid electrolyte and electrodes lead to the capacity of the Li-S battery decaying rapidly, which limits the practical commercial applications of the Li-S battery. Herein, we reported a facile in situ ultraviolet (UV) curing method to prepare a flexible quasi-solid-state composite electrolyte (QSSCE) of poly(propylene glycol)-co-pentaerythritol triacrylate/Li1.5Al0.5Ge1.5(PO4)3 (PPG-co-PETA/LAGP). By combining the high Li-ion conductivity and mechanical strength of inorganic NASICON-structure LAGP and good flexibility of the crosslinked PPG-co-PETA with nanopore structure, the flexible QSSCE with 66.85 wt% LAGP exhibited high Li-ion conductivity of 5.95 × 10−3 S cm−1 at 25 °C, Li-ion transference number of 0.83 and wide electrochemical window of ~5.0 V (vs. Li/Li+). In addition, the application of QSSCE in the Li-S battery could suppress the shuttle effect of polysulfides effectively, thus the Li-S battery possessed the excellent electrochemical cyclic performance, showing the first-cycle discharge-specific capacity of 1508.1 mAh g−1, the capacity retention of 73.6% after 200 cycles with 0.25 C at 25 °C and good rate performance.