Scope and selectivity in palladium-catalyzed directed C–H bond halogenation reactions

Palladium-catalyzed ligand directed C–H activation/halogenation reactions have been extensively explored. Both the nature of the directing group and the substitution pattern on the arene ring of the substrate lead to different reactivity profiles, and often different and complementary products, in t...

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Bibliographic Details
Published inTetrahedron Vol. 62; no. 49; pp. 11483 - 11498
Main Authors Kalyani, Dipannita, Dick, Allison R., Anani, Waseem Q., Sanford, Melanie S.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 04.12.2006
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
MILD
ALKENES
CROSS-COUPLING REACTIONS
CARBON
BROMINATION
CYCLOMETALATED COMPLEXES
ARYL HALIDES
COPPER
AROMATIC-COMPOUNDS
ACTIVATED ARENES
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Summary:Palladium-catalyzed ligand directed C–H activation/halogenation reactions have been extensively explored. Both the nature of the directing group and the substitution pattern on the arene ring of the substrate lead to different reactivity profiles, and often different and complementary products, in the presence and absence of the catalyst. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2006.06.075