Superhydrophobic textile: treatment in aqueous solutions of aluminum salts

• Published in: Cellulose (London) Vol. 28; no. 11; pp. 7455 - 7464
• Main Authors: Endiiarova, E. V., Osipov, A. A., Alexandrov, S. E., Shakhmin, A. L.
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 01.07.2021; Springer Nature B.V
• Subjects: Aluminum chloride; Aluminum oxide; Aqueous solutions; Bioorganic Chemistry; Ceramics; Chemistry; Chemistry and Materials Science; Composites; Contact angle; Glass; Hydrophobic surfaces; Hydrophobicity; Natural Materials; Organic Chemistry; Original Research; Photoelectrons; Physical Chemistry; Polymer Sciences; Spectrum analysis; Sustainable Development; Textiles; X ray photoelectron spectroscopy; Aluminum compounds; Textile materials; Wettability; A contact angle; Superhydrophobicity
• ISSN: 0969-0239; 1572-882X
• DOI: 10.1007/s10570-021-04005-3

Abstarct Textile is currently a promising material. Obtaining hydrophobic surfaces on textiles significantly increases its value when used in various fields. In this work we carried out experiments on textile processing. Treatment of textile materials in solutions containing aluminum allows to obtain a superhydrophobic surface. KAl(SO 4 ) 2 and AlCl 3 solutions were used. It was found that treatment in AlCl 3 solution is more effective and allows to achieve a hydrophobic surface on textile with a contact angle of more than 150º. The hydrophobic surface retained its properties even after 30 days of air storage and after scraping and crumpling of samples. Textile samples were investigated using X-Ray photoelectron spectroscopy (XPS). The X-Ray photoelectron spectroscopy results showed hydrophobicity in the treatment of textile materials is ensured by the formation of aluminum oxide on the surface. The dependence of the coarse calico contact angle on the AlCl 3 solution concentration is determined. which demonstrates that when the concentration of AlCl 3 solution increases (within the limits of variation considered), the contact angle also increases. Graphic abstarct