Rh(III)-catalyzed aromatic C–H bond carbenoid functionalization of triazenes by α-diazomalonate

A Rh(III)-catalyzed aromatic C–H bond carbenoid functionalization of triazenes by α-diazomalonates has been developed, with features of mild reaction condition and high efficiency. Furthermore, the functionalized triazenes could be subject to divergent synthesis. [Display omitted]

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Bibliographic Details
Published inTetrahedron Vol. 72; no. 22; pp. 2725 - 2730
Main Authors Wang, Dahai, Cui, Sunliang
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 02.06.2016
Elsevier
Subjects
Bonding
Carbenoid
catalysts
chemical bonding
chemical reactions
chemical structure
Chemistry
Chemistry, Organic
C–H activation
Divergent synthesis
organic compounds
Physical Sciences
Rh(III) catalysis
rhodium
Science & Technology
Synthesis
Tetrahedrons
Triazene
C–H activation
Divergent synthesis
Carbenoid
Rh(III) catalysis
Triazene
ACTIVATION
ACIDS
INDAZOLES
N BOND
DIAZO-COMPOUNDS
ALKYNES
INDOLES
C-H activation
FACILE SYNTHESIS
BENZAMIDES
VERSATILE
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More Information
Summary:A Rh(III)-catalyzed aromatic C–H bond carbenoid functionalization of triazenes by α-diazomalonates has been developed, with features of mild reaction condition and high efficiency. Furthermore, the functionalized triazenes could be subject to divergent synthesis. [Display omitted]
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2015.06.024