Metal–organic framework-derived porous materials for catalysis

• Published in: Coordination chemistry reviews Vol. 362; pp. 1 - 23
• Main Authors: Chen, Yu-Zhen, Zhang, Rui, Jiao, Long, Jiang, Hai-Long
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.05.2018
• Subjects: Catalysis; Derivatives; Metal–organic frameworks; Porous materials; MAF-6; TCPP; XRD; PBA; QD; MC; MOF-253; rGO/RGO; Catalysis; MO; MP; MS; TOF; Ti–MIL-125; H2bpydc; MIL-88B–NH2; Co–PBA; BTC; DOBDC; NF; FA; Ni–MOF; Fe–MIL-101; OER; BDC; NPC; PCN-224; DRIFTS; Porous materials; F–T synthesis; FTY; NDC; M; ORR; CO2RR; PCN-224(Zn); MIL-53; FTIR; TPT; XAFS; HKUST-1; Al–PCP; GO; CoIIMOF; UiO-66–NH2; Derivatives; Fe–MIL-88A; NENU-5; Fe–MIL-88B; MOF-5; ZIF-67; Metal–organic frameworks; NPs; MOR; Ted; ZIF-8; HER; M-MOF-74; MeIM
• ISSN: 0010-8545; 1873-3840
• DOI: 10.1016/j.ccr.2018.02.008

Metal–organic frameworks (MOFs), constructed by metal ions/clusters and organic linkers, featuring crystalline porous structures, have been intensively employed as templates/precursors for the synthesis of diverse porous materials. The large surface area, high porosity and excellent tailorability of MOFs can be well inherited to their derivatives, making MOF-derived porous materials very promising for catalytic applications. Herein, we systematically summarize the versatile synthetic strategies to fabricate MOF-derived porous materials and give an overview on their recent progress on heterogeneous organocatalysis, photocatalysis and electrocatalysis. Finally, the challenges and prospects related to MOF-derived porous materials for catalysis are also discussed. [Display omitted] •A summary of the versatile synthetic strategies for MOF-derived porous materials.•Recent progress of diverse catalytic reactions over MOF-derived porous materials.•The challenges and prospects related to MOF-derived porous materials for catalysis. Metal–organic frameworks (MOFs), constructed by metal ions/clusters and organic linkers, featuring crystalline porous structures, have been intensively employed as templates/precursors for the synthesis of diverse porous materials including porous carbons, metal-based compounds (such as metal oxides/carbides/phosphides) and their composites. The large surface area, high porosity and excellent tailorability of MOFs can be well inherited to their derivatives, making MOF-derived porous materials very promising for catalytic applications. Herein, we systematically summarize the versatile synthetic strategies to fabricate MOF-derived porous materials and give an overview on their recent progress on organic heterogeneous catalysis, photocatalysis and electrocatalysis. Finally, the challenges and prospects related to MOF-derived porous materials for catalysis are also discussed.