Modulation of crystal water in cobalt phosphate for promoted water oxidation

Herein, low-dimensional cobalt phosphate (Co-Pi) catalysts with variable contents of crystal water were fabricated for oxygen evolution reaction (OER). Owing to the optimized electronic structure, rich surface sites and favorable charge transport ability, Co-Pi tetrahydrate exhibits remarkable OER a...

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Published inChemical communications (Cambridge, England) Vol. 56; no. 33; pp. 4575 - 4578
Main Authors Qi, Jindi, Xie, Junfeng, Wei, Zimeng, Lou, Shanshan, Hao, Pin, Lei, Fengcai, Tang, Bo
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 28.04.2020
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Summary:Herein, low-dimensional cobalt phosphate (Co-Pi) catalysts with variable contents of crystal water were fabricated for oxygen evolution reaction (OER). Owing to the optimized electronic structure, rich surface sites and favorable charge transport ability, Co-Pi tetrahydrate exhibits remarkable OER activity with a low overpotential, large current density and high intrinsic activity, and it is proved to be the optimal Co-Pi phase for OER. Cobalt phosphate tetrahydrate was identified as the optimal Co-Pi phase for electrocatalytic oxygen evolution reaction.
Bibliography:Electronic supplementary information (ESI) available: The experimental section and the additional characterization. See DOI
10.1039/d0cc01023e
ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc01023e