Polypyrrole-Fe2O3 nanohybrid materials for electrochemical storage

• Published in: Journal of solid state electrochemistry Vol. 11; no. 3; pp. 398 - 406
• Main Authors: Mallouki, M., Tran-Van, F., Sarrazin, C., Simon, P., Daffos, B., De, A., Chevrot, C., Fauvarque, J. F.
• Format: Journal Article
• Language: English
• Published: Springer Verlag 01.03.2007
• Subjects: Chemical Sciences; Material chemistry; Conducting polymers; Nanocomposites; Room temperature ionic liquid; Electrochemical storage
• ISSN: 1432-8488; 1433-0768
• DOI: 10.1007/s10008-006-0161-8

We report on the synthesis and electrochemical characterization of nanohybrid polypyrrole (PPy) (PPy/Fe2O3) materials for electrochemical storage applications. We have shown that the incorporation of nanoparticles inside the PPy notably increases the charge storage capability in comparison to the “pure” conducting polymer. Incorporation of large anions, i.e., paratoluenesulfonate, allows a further improvement in the capacity. These charge storage modifications have been attributed to the morphology of the composite in which the particle sizes and the specific surface area are modified with the incorporation of nanoparticles. High capacity and stability have been obtained in PC/NEt4BF4 (at 20 mV/s), i.e., 47 mAh/g, with only a 3% charge loss after one thousand cyles. The kinetics of charge–discharge is also improved by the hybrid nanocomposite morphology modifications, which increase the rate of insertion–expulsion of counter anions in the bulk of the film. A room temperature ionic liquid such as imidazolium trifluoromethanesulfonimide seems to be a promising electrolyte because it further increases the capacity up to 53 mAh/g with a high stability during charge–discharge processes.