Degradation of poly(l-lactide) under CO2 laser treatment above the ablation threshold

• Published in: Polymer degradation and stability Vol. 109; pp. 97 - 105
• Main Authors: Antończak, Arkadiusz J., Stępak, Bogusz D., Szustakiewicz, Konrad, Wójcik, Michał R., Abramski, Krzysztof M.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.11.2014; Elsevier
• Subjects: Applied sciences; ATR-FTIR; CO2 laser modification; Coating, metallization, dyeing; DSC; Exact sciences and technology; GPC/SEC; Machinery and processing; Plastics; Poly(l-lactide); Polymer degradation; Polymer industry, paints, wood; Technology of polymers; GPC/SEC; CO2 laser modification; Poly(l-lactide); Polymer degradation; DSC; ATR-FTIR; Differential scanning calorimetry; Optically active polymer; Laser assisted processing; laser modification; Poly(L-lactide); Experimental study; CO; Lactone polymer; Quantitative surface analysis; Gas chromatography; Wettability; laser; Reaction mechanism; Surface properties; Photochemical stability; Photoelectron spectrometry; Chemical composition; Fourier-transformed infrared spectrometry; Photochemical degradation
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2014.07.004

In this paper, we present an analysis of changes in material properties in the heat affected zone HAZ induced by the CO2 laser at the fluence well above the ablation threshold. The complexity of the processes of decomposition implies the need for simultaneous use of many selective analytical techniques which complement each other to give a full image of the changes. Introduced changes were characterized using Differential Scanning Calorimetry (DSC), Gel Permeation Chromatography (GPC/SEC), X-ray Photoelectron Spectroscopy (XPS), Attenuated Total Reflectance-Fourier Transform Infrared spectroscopy (ATR-FTIR) and Wettability (Contact Angle) measurement. It turns out that CO2 laser processing of poly(l-lactide) mainly induces surface changes. However, oxidation of the surface was not observed. We recorded a bimodal distribution, a significant increase in polydispersity index and some reduction in the molecular weight. Infrared spectroscopy in turn revealed the existence of absorption bands, characteristic for the vinyl groups (RCHCH2). The appearance of these bands indicates that the decomposition of the polymer occurred, among others, by means of the cis-elimination reaction.