Directed cleavage of carbon—tin bonds by palladium

The ligands 8-(trimethylstannyl)methylquinoline, n-Bu 3Sn(CH 2) 3NMe 2 and Ph 3Sn(CH 2) 3,NMe 2 react with (C 6H 5CN) 2PdCl 2 to give five-membered palladium chelates. in which the nitrogen atom was able to direct palladium insertion into a specific carbon—tin bond. The X-ray crystal structure of th...

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Published inJournal of organometallic chemistry Vol. 299; no. 3; pp. 297 - 309
Main Authors Suggs, J.William, Lee, Ken.S.
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 28.01.1986
Elsevier Science
Subjects
Applied sciences
Chemistry
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Organic chemistry
Organometalloidal and organometallic compounds
Other techniques and industries
Physics
Preparations and properties
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Transition metals derivatives
Tertiary phosphine
Molecular structure
Palladium Organic compounds
Organic ligand
Transition metal Complexes
Experimental study
X ray diffraction
Scission
Mu complex
Dinuclear complex
Chloro complex
Dimer
Platinoid Complexes
Tin Organic compounds
Crystalline structure
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Summary:The ligands 8-(trimethylstannyl)methylquinoline, n-Bu 3Sn(CH 2) 3NMe 2 and Ph 3Sn(CH 2) 3,NMe 2 react with (C 6H 5CN) 2PdCl 2 to give five-membered palladium chelates. in which the nitrogen atom was able to direct palladium insertion into a specific carbon—tin bond. The X-ray crystal structure of the simple chelate [(Me 2N(CH 2) 3)PdCl] 2 is presented.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(86)84004-9