The Fractionation of Corn Stalk Components by Hydrothermal Treatment Followed by Ultrasonic Ethanol Extraction

• Published in: Energies (Basel) Vol. 15; no. 7; p. 2616
• Main Authors: Zhang, Nianze, Tian, Chunyan, Fu, Peng, Yuan, Qiaoxia, Zhang, Yuchun, Li, Zhiyu, Yi, Weiming
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.04.2022
• Subjects: Acids; Alternative energy; Biomass; Cellulose; Clean technology; components fractionation; Efficiency; Ethanol; ethanol treatment; Experiments; Fourier transforms; Fractionation; Hemicellulose; Hydrolysates; Hydrothermal treatment; Infrared analysis; Lignin; Lignocellulose; Mass spectrometry; Scientific imaging; Solvents; Sonication; ultrasonic; Ultrasonic imaging; United States > US; China
• ISSN: 1996-1073; 1996-1073
• DOI: 10.3390/en15072616

The fractionation of components of lignocellulosic biomass is important to be able to take advantage of biomass resources. The hydrothermal–ethanol method has significant advantages for fraction separation. The first step of hydrothermal treatment can separate hemicellulose efficiently, but hydrothermal treatment affects the efficiency of ethanol treatment to delignify lignin. In this study, the efficiency of lignin removal was improved by an ultrasonic-assisted second-step ethanol treatment. The effects of ultrasonic time, ultrasonic temperature, and ultrasonic power on the ultrasonic ethanol treatment of hydrothermal straw were investigated. The separated lignin was characterized by solid product composition analysis, FT-IR, and XRD. The hydrolysate was characterized by GC-MS to investigate the advantage on the products obtained by ethanol treatment. The results showed that an appropriate sonication time (15 min) could improve the delignification efficiency. A proper sonication temperature (180 °C) can improve the lignin removal efficiency with a better retention of cellulose. However, a high sonication power 70% (840 W) favored the retention of cellulose and lignin removal.