Role of the Polar Proportion of Compound Collectors in Low-Rank Coal Flotation Upgrading: Insights from the Molecular Scale

• Published in: Minerals (Basel) Vol. 13; no. 4; p. 524
• Main Authors: Liu, Junling, Bao, Xicheng, Hao, Yesheng, Liu, Jincheng, Cheng, Yulong, Zhang, Rui, Xing, Yaowen, Gui, Xiahui, Li, Jihui, Avid, Budeebazar
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.04.2023
• Subjects: Acids; Adhesion; Adsorption; Aggregation; Bubbles; Coal; Coal gasification; Collectors; compound collector; Dodecane; Electron microscopes; Energy; Flotation; Hydrophobicity; Kerosene; low-rank coal flotation; MD simulation; Molecular dynamics; Monounsaturated fatty acids; Oil; Oleic acid; optimal proportion; Particle size; Spreading; Surfactants; China; United States > US
• ISSN: 2075-163X; 2075-163X
• DOI: 10.3390/min13040524

The compound collector, composed of polar and nonpolar parts, is a current research hotspot in low-rank coal (LRC) flotation because of its outstanding flotation efficiency and cost-effectiveness. However, the selection of compound proportions lacks theoretical guidance. In this study, we comprehensively investigate the internal mechanism underlying the influence of the compound proportion (oleic acid (OA):dodecane (DD)) on LRC flotation. The molecular dynamics (MD) simulation between bubble and oil film was simultaneously employed to study the surface interactions between three phases in contact. The compound proportion of OA:DD = 1:3 was found to be the most conductive for Zhuanlongwan coal flotation, which provides a robust collecting capacity while minimizing excessive interaction with water. Thus, the spreading area is the largest and the interaction energy between collectors and LRC is the highest. Additionally, the oil film formed at this ratio has the best hydrophobicity, resulting in the fastest adhesion speed of the bubble and the most stable bubble adhesion. Proportions of OA:DD above 1:3 promote self-aggregation of polar collectors, leading to a worsened spreading of the oil film. Conversely, proportions below 1:3 result in weak interaction with LRC, leading to a smaller spreading area and reduced hydrophobicity. Ultimately, we propose the LRC–compound collector matching principle, which suggests that the best proportion of compound collectors fits well with the oxygen-containing sites on the LRC surface.