Magnetic Amphiphilic Composites Applied for the Treatment of Biodiesel Wastewaters

• Published in: Applied sciences Vol. 2; no. 2; pp. 513 - 524
• Main Authors: Lemos, Bruno R. S., Teixeira, Ana Paula C., Ardisson, José D., Macedo, Waldemar A. A., Fernandez-Outon, Luis E., Amorim, Camila C., Moura, Flávia C. C., Lago, Rochel M.
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.06.2012
• Subjects: Biodiesel fuels; biodiesel wastewater; breaking emulsions process; Carbon; Chemical oxygen demand; Chemical vapor deposition; chrysotile; Electronic mail systems; Ethanol; Hydrophilic surfaces; magnetic amphiphilic systems; Magnetic fields; Nanostructured materials; Spectrum analysis; Temperature; Brazil
• ISSN: 2076-3417; 2076-3417
• DOI: 10.3390/app2020513

In this work, new magnetic amphiphilic composites were prepared by chemical vapor deposition with ethanol on the surface of hydrophilic natural chrysotile matrix containing Fe catalyst. XRD, Raman, Mössbauer and SEM analyses suggest the formation of a complex nanostructured material composed of hydrophobic carbon nanotubes/nanofibers grown on the hydrophilic surface of the MgSi fiber mineral and the presence of Fe metallic nanoparticles coated by carbon. These nanostructured particles show amphiphilic properties and interact very well with both oil and aqueous phases. When added to emulsions the amphiphilic particles locate on the oil/water interface and, under a magnetic field, the oil droplets collapsed leading to the separation of the aqueous and oil phases. Preliminary work showed excellent results on the use of these particles to break wastewater emulsions in the biodiesel process.