A study of Sm-substituted SrM magnets sintered using hydrothermally synthesised powders

• Published in: Journal of magnetism and magnetic materials Vol. 298; no. 2; pp. 122 - 131
• Main Authors: Wang, J.F., Ponton, C.B., Harris, I.R.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.03.2006; Elsevier Science
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Cross-disciplinary physics: materials science; rheology; Domain effects, magnetization curves, and hysteresis; Exact sciences and technology; Hydrothermal synthesis; Magnetic properties; Magnetic properties and materials; Magnetization curves, magnetization reversal, hysteresis, barkhausen and related effects; Materials science; Materials synthesis; materials processing; Physics; Sm substitution; Sr hexaferrite magnet; X-ray diffraction; Sm substitution; Hydrothermal synthesis; 75.50.Gg; 75.50.Ww; X-ray diffraction; Sr hexaferrite magnet; 74.25.Ha; Magnetic properties; Grain size; Grain boundaries; Hexagonal ferrites; Grain growth; Solubility; Ferromagnetic materials; 74.25.Ha Sr hexaferrite magnet; Strontium oxides; Ion substitution; Powder technology; Anisotropy; Sintering; Coercive force; Iron oxides
• ISSN: 0304-8853
• DOI: 10.1016/j.jmmm.2005.03.012

Anisotropic SrM magnets with Sm substitution, which is observed to have the largest beneficial effect both on the coercivity and on the inhibition of grain growth at high temperature among the other elements such as La, Nd and Pr, were investigated. The average grain size of the samples decreases with increasing Sm/Sr ratio. All the magnets with Sm additions exhibit a bigger coercivity and remanence than those of the SrM magnet without Sm and the coercivity of the magnets increases with increasing Sm/Sr ratio. EDX quantitative analysis suggests that the solubility of Sm 3+ in the SrM-type structure is very small and that the Sm 3+ preferably goes into SrFeO 3− x , which is probably located around the SrM grain boundaries. The coercivity mechanism of the magnets is nucleation controlled. The formation and the distribution of the SrFeO 3− x phase around the SrM grain boundraies probably provides the inhibition of SrM grain growth, the reduction of the reverse domain nucleation at the grain surface and the isolation of the SrM grains. All these factors would contribute to the improvements of the coercivity of the magnets with Sm additions.