Bispidine-Based Macrocycles: Achievements and Perspectives
This review presents all currently known macroheterocyclic compounds that include a bispidine (3,7-diazabicyclo[3.3.1]nonane) fragment in their structure. A classification of bispidine-containing macroheterocycles, which is based on the ring size and the nature of bispidinic nitrogen atoms, is sugge...
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| Published in | Organics (Basel) Vol. 4; no. 3; pp. 417 - 437 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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01.09.2023
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| Abstract | This review presents all currently known macroheterocyclic compounds that include a bispidine (3,7-diazabicyclo[3.3.1]nonane) fragment in their structure. A classification of bispidine-containing macroheterocycles, which is based on the ring size and the nature of bispidinic nitrogen atoms, is suggested. Synthetic approaches to the studied compounds are classified and considered. The features of the crystal structures and solution behavior of bispidine macroheterocycles are analyzed. Prospects for the development of these organic receptors are proposed. |
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| AbstractList | This review presents all currently known macroheterocyclic compounds that include a bispidine (3,7-diazabicyclo[3.3.1]nonane) fragment in their structure. A classification of bispidine-containing macroheterocycles, which is based on the ring size and the nature of bispidinic nitrogen atoms, is suggested. Synthetic approaches to the studied compounds are classified and considered. The features of the crystal structures and solution behavior of bispidine macroheterocycles are analyzed. Prospects for the development of these organic receptors are proposed. |
| Author | Kalinin, Mikhail A. Vatsadze, Sergey Z. Medved’ko, Aleksei V. Gaisen, Savelii V. |
| Author_xml | – sequence: 1 givenname: Aleksei V. orcidid: 0000-0002-8731-6934 surname: Medved’ko fullname: Medved’ko, Aleksei V. – sequence: 2 givenname: Savelii V. surname: Gaisen fullname: Gaisen, Savelii V. – sequence: 3 givenname: Mikhail A. orcidid: 0000-0002-0056-4813 surname: Kalinin fullname: Kalinin, Mikhail A. – sequence: 4 givenname: Sergey Z. orcidid: 0000-0001-7884-8579 surname: Vatsadze fullname: Vatsadze, Sergey Z. |
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| Cites_doi | 10.6060/mhc200814k 10.3987/COM-07-11063 10.1039/cc9960002093 10.1002/3527603964 10.1070/MC1992v002n04ABEH000187 10.1016/j.tet.2015.08.072 10.1016/j.jorganchem.2021.121945 10.1107/S2056989016007556 10.1021/ol202840s 10.1007/978-981-15-2686-2 10.1134/S0012500822010013 10.1007/978-3-319-31867-7 10.1021/ic500476u 10.1134/S0036023613060156 10.1039/9781782623113 10.1016/0040-4020(95)00161-Z 10.1021/ja00030a077 10.1107/S1600536812030644 10.1016/j.tetlet.2013.02.028 10.1134/S1070428023030090 10.1002/ejoc.201601365 10.1016/j.mencom.2020.03.008 10.1016/j.mencom.2019.11.004 10.1002/1521-3773(20010702)40:13<2465::AID-ANIE2465>3.0.CO;2-X 10.1002/hlca.19940770320 10.1039/C4SC03089C 10.1007/1-4020-3687-6 10.1016/j.molstruc.2014.09.088 10.1107/S1600536812027274 10.1134/S0036023614100180 10.3390/molecules27020430 10.1016/0006-291X(67)90295-1 10.1038/s41557-020-00620-y 10.1016/S0301-0104(02)00331-2 10.1007/s10593-008-0084-7 10.1134/S0036023616020169 10.1039/D1CS00175B 10.1246/cl.2000.620 10.1021/acs.joc.6b00250 10.1002/9781119092599 10.1007/BF02150990 10.1016/j.mencom.2018.05.028 10.1016/S0040-4039(01)00341-0 10.1070/RCR5011 10.1002/9780470980200 |
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| SubjectTerms | 3,7-diazabicyclo[3.3.1]nonane bispidine Copper crown ethers Hydrogen bonds macroheterocycles Mannich reaction Nitrogen supramolecular chemistry |
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| Title | Bispidine-Based Macrocycles: Achievements and Perspectives |
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