Bispidine-Based Macrocycles: Achievements and Perspectives

This review presents all currently known macroheterocyclic compounds that include a bispidine (3,7-diazabicyclo[3.3.1]nonane) fragment in their structure. A classification of bispidine-containing macroheterocycles, which is based on the ring size and the nature of bispidinic nitrogen atoms, is sugge...

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Published inOrganics (Basel) Vol. 4; no. 3; pp. 417 - 437
Main Authors Medved’ko, Aleksei V., Gaisen, Savelii V., Kalinin, Mikhail A., Vatsadze, Sergey Z.
Format Journal Article
LanguageEnglish
Published Leuven MDPI AG 01.09.2023
Subjects
3,7-diazabicyclo[3.3.1]nonane
bispidine
Copper
crown ethers
Hydrogen bonds
macroheterocycles
Mannich reaction
Nitrogen
supramolecular chemistry
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Summary:This review presents all currently known macroheterocyclic compounds that include a bispidine (3,7-diazabicyclo[3.3.1]nonane) fragment in their structure. A classification of bispidine-containing macroheterocycles, which is based on the ring size and the nature of bispidinic nitrogen atoms, is suggested. Synthetic approaches to the studied compounds are classified and considered. The features of the crystal structures and solution behavior of bispidine macroheterocycles are analyzed. Prospects for the development of these organic receptors are proposed.
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ISSN:2673-401X
2673-401X
DOI:10.3390/org4030030