X-ray photoelectron spectra of Pd(II) and Pt(II) complexes with 1,3-thiazolidine-2-thione. A quantum mechanics study on the free ligand

• Published in: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 57; no. 5; pp. 1073 - 1083
• Main Authors: Atzei, D, De Filippo, D, Rossi, A, Porcelli, M
• Format: Journal Article
• Language: English
• Published: England Elsevier B.V 01.04.2001
• Subjects: 1,3-thiazolidine-2-thione; Ligands; Metal complexes; Palladium - chemistry; Platinum - chemistry; Quantum mechanics; Quantum Theory; Spectrometry, X-Ray Emission; Stereoisomerism; Thermodynamics; Thiazoles - chemistry; Thiazolidines; ttz; X-ray Photoelectron spectroscopy; 1,3-thiazolidine-2-thione; ttz; X-ray Photoelectron spectroscopy; Metal complexes; Quantum mechanics
• ISSN: 1386-1425
• DOI: 10.1016/S1386-1425(00)00424-8

Metal complexes of general formula M(ttz) 2X 2 (with M=Pd(II) or Pt(II); X=Cl or Br; ttz=1,3-thiazolidine-2-thione) have been synthetized as crystalline compounds and studied by means of X-ray Photoelectron Spectroscopy (XPS). The chemical shift of core level signals showed that ttz is bonded to the metal through the thioketonic sulphur atom and that electronic charge redistribution in the ligand takes place after complexation. No metal-nitrogen bonds are present. This is consistent with the results of all the quantum mechanical models according to which hydrogen is bound to nitrogen, even in the hydrogen bonded complex, making the latter rather unavailable to coordination