A new family of supramolecular multiferrocenyl rhomboids：Synthesis,characterization,and their electrochemical behavior
Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, a...
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| Published in | Chinese chemical letters Vol. 24; no. 6; pp. 471 - 474 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.06.2013
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China |
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| Abstract | Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated. |
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| AbstractList | Two novel, supramolecular, multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60° ferrocenyl donor precursor 1via coordination-driven self-assembly. The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR (1H and 31P), CSI–TOF-MS, and PM6 semi-empirical molecular simulation, and their electrochemical behaviors have been investigated.
Two novel, supramolecular, multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60° ferrocenyl donor precursor 1via coordination-driven self-assembly. The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR (1H and 31P), CSI–TOF-MS, and PM6 semi-empirical molecular simulation, and their electrochemical behaviors have been investigated. Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated. |
| Author | Jiang-Kun Ou-Yang Li-Jun Chen Lin Xu Cui-Hong Wang Hai-Bo Yang |
| AuthorAffiliation | Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China |
| AuthorAffiliation_xml | – name: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China |
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| Cites_doi | 10.1021/ja020833k 10.1021/cr200077m 10.1021/ja109380u 10.1039/b811712h 10.1021/jo201979d 10.1126/science.1067794 10.1021/ol9911425 10.1021/ar068185n 10.1021/jo201594u 10.1021/ac0603476 10.1021/ar600029p 10.1021/om1008605 10.1021/cr0101510 10.1021/ja0117478 10.1021/jo801692v 10.1021/om2003305 10.1039/a604225b |
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| Keywords | Supromolecular metallacycle Multiferrocenyl rhomboid Electrochemical behavior Coordination-driven self-assembly |
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| Notes | Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated. 11-2710/O6 Supromolecular metallacycle Coordination-driven self-assembly Multiferrocenyl rhomboid Electrochemical behavior |
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| Snippet | Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via... Two novel, supramolecular, multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60° ferrocenyl donor precursor 1via... |
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| SubjectTerms | Coordination-driven self-assembly Electrochemical behavior Multiferrocenyl rhomboid Supromolecular metallacycle 二茂铁基 合成 家庭 核磁共振 电化学行为 菱形 表征 超分子 |
| Title | A new family of supramolecular multiferrocenyl rhomboids：Synthesis,characterization,and their electrochemical behavior |
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