A new family of supramolecular multiferrocenyl rhomboids：Synthesis,characterization,and their electrochemical behavior

Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, a...

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Bibliographic Details
Published inChinese chemical letters Vol. 24; no. 6; pp. 471 - 474
Main Authors Ou-Yang, Jiang-Kun, Chen, Li-Jun, Xu, Lin, Wang, Cui-Hong, Yang, Hai-Bo
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.06.2013
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China
Subjects
Coordination-driven self-assembly
Electrochemical behavior
Multiferrocenyl rhomboid
Supromolecular metallacycle
二茂铁基
合成
家庭
核磁共振
电化学行为
菱形
表征
超分子
Supromolecular metallacycle
Multiferrocenyl rhomboid
Electrochemical behavior
Coordination-driven self-assembly
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Summary:Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated.
Bibliography:Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated.
11-2710/O6
Supromolecular metallacycle Coordination-driven self-assembly Multiferrocenyl rhomboid Electrochemical behavior
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2013.03.055