A New Insight into the Genesis of Graphite Deposits in Madagascar Using U–Pb Zircon Dating and Electron Microprobe Analysis

• Published in: Minerals (Basel) Vol. 14; no. 5; p. 484
• Main Authors: Yang, Ming-Jian, Di, Yong-Jun, Zhang, Da, Wu, Da-Tian, Fang, Ye, Zhang, Xin-Ming
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.05.2024
• Subjects: Biotite; Carbon; Case studies; Deposits; Electron microprobe; electron microprobe analysis; Electron probe microanalysis; Electron probes; Fluids; Geology; Graphite; graphite deposit; Investigations; Madagascar; mantle-derived fluid filling; Metamorphism; Metamorphism (Geology); Mineral assemblages; Mineralization; Minerals; Organic matter; Pegmatite; Rocks, Metamorphic; Sediments; Sediments (Geology); Shear; Shear zone; Trends; U–Pb geochronology; Zircon; United Kingdom; China; Madagascar; Antananarivo Madagascar
• ISSN: 2075-163X; 2075-163X
• DOI: 10.3390/min14050484

Madagascar is globally recognized as an important producer of high-quality flaky graphite. However, current research on graphite deposits in Madagascar remains insufficient. Previous studies have linked the genesis of Madagascan graphite deposits to the metamorphism of sedimentary organic matter. Here, we provide a case study of graphite deposits in Madagascar, combining new data from the Ambahita graphite deposit (AMG) in southern Madagascar with data from the Antanisoa graphite deposit (ANG) in central Madagascar and the Vohitasara graphite deposit (VOG) on the east coast of Madagascar. We note that the mineral assemblages of graphite-bearing rocks in the AMG, ANG, and VOG are not typical of metamorphic mineral assemblages but rather the results of filling and metasomatism by mantle-derived fluids that occurred after peak metamorphism. Electron microprobe analysis indicates that the graphite of the AMG, VOG, and ANG is usually associated with phlogopite or Mg-biotite; the phlogopite shares a common genesis with other widespread phlogopite deposits across Madagascar. We reveal that the distribution of graphite deposits in Madagascar is primarily controlled by ductile shear zones between blocks. Ductile shear zones that extend deep into the mantle can provide an ideal migration channel and architecture for the emplacement of mantle-derived fluids. The graphite mineralization formed no earlier than the peak metamorphism (490 Ma) and no later than the intrusion of pegmatite veins (389 ± 5 Ma). The distribution of graphite deposits, graphite orebody morphologies, mineral associations, and geochemical data suggest that the genesis of graphite deposits in Madagascar is linked to mantle-derived fluid filling rather than the metamorphism of sediments, as previously suggested. These findings have important implications for similar deposits in Madagascar and potentially globally.