Synthetic approaches to carnegine, a simple tetrahydroisoquinoline alkaloid

The different approaches towards the total synthesis of carnegine, a simple tetrahydroisoquinoline alkaloid isolated from several Cactaceae and Chenopodiaceae as well as other plants, are presented. Emphasis is placed on the various enantioselective strategies leading to the natural product in chira...

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Bibliographic Details
Published inTetrahedron Vol. 60; no. 47; pp. 10575 - 10610
Main Authors Bracca, Andrea B.J., Kaufman, Teodoro S.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 15.11.2004
Subjects
Carnegine
Cyclization
Enantioselective synthesis
Plant alkaloids
Simple tetrahydroisoquinolines
Synthesis
Plant alkaloids
Carnegine
Synthesis
Cyclization
Simple tetrahydroisoquinolines
Enantioselective synthesis
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Summary:The different approaches towards the total synthesis of carnegine, a simple tetrahydroisoquinoline alkaloid isolated from several Cactaceae and Chenopodiaceae as well as other plants, are presented. Emphasis is placed on the various enantioselective strategies leading to the natural product in chiral form. Graphical Abstract
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2004.08.033