Influence of asphaltenes on coke formation during the thermal cracking of different Brazilian distillation residues

• Published in: Fuel (Guildford) Vol. 86; no. 4; pp. 619 - 623
• Main Authors: Gonçalves, Maria Luisa A., Ribeiro, Daniel A., Teixeira, Ana Maria R.F., Teixeira, Marco Antonio G.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.03.2007; Elsevier
• Subjects: Applied sciences; Asphaltenes; Crude oil, natural gas and petroleum products; Energy; Exact sciences and technology; Fuels; Heavy residue; Processing of crude oil and oils from shales and tar sands. Processes. Equipment. Refinery and treatment units; Thermogravimetry; Asphaltenes; Heavy residue; Thermogravimetry; Asphaltene; Distillation; Reduced crude; Carbonaceous materials; Thermal cracking; Crude oil; Coke; Refinery; Gravity
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2006.08.022

This research was conducted to allow the investigation on the influence of asphaltenes on coke formation, during the thermal cracking of atmospheric distillation residues, using thermogravimetry. Asphaltenes of five refinery atmospheric distillation residues, of different API gravity Brazilian crude oils, were isolated by the IP143 methodology. The original samples and the same samples, after asphaltenes extraction, were analyzed by thermogravimetry. It was observed that the heavier the sample, the higher was the contribution of the asphaltenes to the coke formation. The extracted asphaltenes were analyzed under the same TG conditions of the atmospheric distillation residues and all asphaltenes appeared to form approximately the same amount of carbonaceous residue after the thermal cracking. Heavier and lighter atmospheric distillation residues were doped with 10%, 20% and 30% amount of asphaltenes and, again, the higher the asphaltenes amount, the higher would be the carbonaceous material formation. The same tendency was observed for both doped samples.