Ultrasound effects on metallic (Fe and Cr); iron sesquioxides (α-,γ-Fe 2O 3); calcite; copper, lead and manganese oxides as powders

Different kind of materials, as powders, were submitted to ultrasound after mixing in water, dodecane or dilute acetic acid (5%). After treatment, firstly a decrease of particle size, and secondly the formation of unexpected and unknown compounds was observed on a mesoscopic scale (CaO from CaCO 3 f...

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Published inUltrasonics sonochemistry Vol. 7; no. 1; pp. 25 - 33
Main Authors Gasgnier, M, Beaury, L, Derouet, J
Format Journal Article
LanguageEnglish
Published Netherlands Elsevier B.V 2000
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Summary:Different kind of materials, as powders, were submitted to ultrasound after mixing in water, dodecane or dilute acetic acid (5%). After treatment, firstly a decrease of particle size, and secondly the formation of unexpected and unknown compounds was observed on a mesoscopic scale (CaO from CaCO 3 for example). For iron and iron oxides, it was found that the magnetic properties (susceptibility and effective magnetic moment) were changed slightly. A shift in the Morin temperature transition for α-Fe 2O 3 was attributed to the formation of impurities. For inorganic oxides (Cu 2O, PbO, Pb 3O 4 and Mn 3O 4) sonicated in dilute acetic acid, the formation of metallic acetates is easily achieved and it is rapid (10 s for PbO).
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1350-4177
1873-2828
DOI:10.1016/S1350-4177(99)00024-3