Dissolution of Low Enriched Uranium from Experimental Breeder Reactor-II Fuel

• Published in: Separation science and technology Vol. 54; no. 12; pp. 1893 - 1903
• Main Authors: Daniel, William E., Rudisill, Tracy S., O'Rourke, Patrick E., Almond, Philip M.
• Format: Journal Article
• Language: English
• Published: Abingdon Taylor & Francis 13.08.2019; Taylor & Francis Ltd
• Subjects: Aluminum base alloys; Analytical methods; Breeder reactors; Canyons; Carbon; Carbon steel; Carbon steels; Cycle time; Dissolution; dissolver; Dissolvers; Dissolving; Electrochemistry; H-Canyon; Hydrogen production; Ingots; Laboratories; Mass spectrometry; Mass spectroscopy; Metals; NUCLEAR FUEL CYCLE AND FUEL MATERIALS; Nuclear fuels; Raman spectroscopy; Reactors; Spent nuclear fuels; Steel; Uranium
• ISSN: 0149-6395; 1520-5754
• DOI: 10.1080/01496395.2019.1578804

A dissolution flowsheet for the Low Enriched Uranium (LEU) ingots generated at the Idaho National Laboratory (INL) from the electrochemical processing of the EBR-II fuel was demonstrated at the laboratory scale. Dissolution experiments were performed using samples of the LEU and a carbon steel can and an integrated experiment was performed in which an Al 1100 alloy was dissolved as a surrogate for Spent Nuclear Fuel (SNF) followed by the dissolution of samples of the LEU and carbon steel can to demonstrate the complete flowsheet. The flowsheet allows the dissolution of a SNF batch in an H-Canyon dissolver using existing flowsheets followed by the dissolution of nominally 75 kg of LEU in the 6.4D dissolver or 45 kg of LEU in the 6.1D dissolver which were recovered from the Experimental Breeder Reactor-II (EBR-II) fuel. In the demonstration experiment, the rate of dissolution of the LEU metal was significantly slower than the dissolution rate of the Al 1100 alloy (4.7 versus 27 mg/min/cm 2 ) which projects to a longer cycle time for the LEU metal (compared to a SNF charge). The H 2 generation rates from the dissolution of samples of the LEU metal and a carbon steel can were monitored by mass spectrometry and Raman spectroscopy and were shown to be inconsequential; therefore, the dissolution of the LEU ingots has no significant impact on the generation of H 2 .