Preparation, single-crystal X-ray diffraction and high-resolution NMR spectroscopic analyses of N-[(1,4-anhydro-5-deoxy-2,3- O-isopropylidene- d, l-ribitol)-5-yl]trimethylammonium iodide

• Published in: Carbohydrate research Vol. 341; no. 11; pp. 1916 - 1921
• Main Authors: Dmochowska, Barbara, Skorupa, Eugenia, Pellowska-Januszek, Lucyna, Czarkowska, Monika, Sikorski, Artur, Wiśniewski, Andrzej
• Format: Journal Article
• Language: English
• Published: OXFORD Elsevier Ltd 14.08.2006; Elsevier
• Subjects: 1,4-Anhydro- d, l-ribitol; 1H, 13C NMR spectroscopy; Biochemistry & Molecular Biology; Chemistry; Chemistry, Applied; Chemistry, Organic; Crystallization; Crystallography, X-Ray; Iodides - chemistry; Life Sciences & Biomedicine; Magnetic Resonance Spectroscopy; Methylamines - chemistry; Models, Molecular; Molecular Structure; Physical Sciences; Quaternary Ammonium Compounds - chemical synthesis; Quaternary Ammonium Compounds - chemistry; Quaternary ammonium salt; Ribitol - chemistry; Science & Technology; X-ray crystallography; X-Ray Diffraction; X-ray crystallography; Quaternary ammonium salt; 1H, 13C NMR spectroscopy; 1,4-Anhydro- d, l-ribitol; C-13 NMR spectroscopy; H-1; 1,4-anhydro-D,L-ribitol; quaternary ammonium salt
• ISSN: 0008-6215; 1873-426X
• DOI: 10.1016/j.carres.2006.04.036

The synthesis and isolation of 1,4-anhydro-5-deoxy-5-iodo-2,3- O-isopropylidene- d, l-ribitol and N-[(1,4-anhydro-5-deoxy-2,3- O-isopropylidene- d, l-ribitol)-5-yl]trimethylammonium iodide are described. The products were examined by 1H, 13C NMR spectroscopy, and N-[(1,4-anhydro-5-deoxy-2,3- O-isopropylidene- d, l-ribitol)-5-yl]trimethylammonium iodide was additionally analyzed by X-ray crystallography.