Individual extraction constants of some divalent metal cations in the two-phase water–nitrobenzene system
From extraction experiments and γ -activity measurements, the exchange extraction constants corresponding to the general equilibrium M 2+ (aq) + Sr 2+ (nb) ⇄ M 2+ (nb) + Sr 2+ (aq) taking part in the two-phase water–nitrobenzene system (M 2+ = Mg 2+ , Ca 2+ , Ba 2+ , Cu 2+ , Zn 2+ , Cd 2+ , Pb 2+ ,...
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| Published in | Journal of radioanalytical and nuclear chemistry Vol. 285; no. 3; pp. 683 - 686 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Dordrecht
Springer Netherlands
01.09.2010
Springer |
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| Online Access | Get full text |
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| Abstract | From extraction experiments and
γ
-activity measurements, the exchange extraction constants corresponding to the general equilibrium M
2+
(aq) + Sr
2+
(nb) ⇄ M
2+
(nb) + Sr
2+
(aq) taking part in the two-phase water–nitrobenzene system (M
2+
= Mg
2+
, Ca
2+
, Ba
2+
, Cu
2+
, Zn
2+
, Cd
2+
, Pb
2+
,
, Mn
2+
, Fe
2+
, Co
2+
, Ni
2+
; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the individual extraction constants of the M
2+
cations in the mentioned two-phase system were calculated; they were found to increase in the following cation order:
< Zn
2+
, Ni
2+
< Cu
2+
, Cd
2+
< Co
2+
< Mg
2+
< Ca
2+
< Mn
2+
, Fe
2+
< Sr
2+
< Pb
2+
< Ba
2+
. |
|---|---|
| AbstractList | From extraction experiments and
γ
-activity measurements, the exchange extraction constants corresponding to the general equilibrium M
2+
(aq) + Sr
2+
(nb) ⇄ M
2+
(nb) + Sr
2+
(aq) taking part in the two-phase water–nitrobenzene system (M
2+
= Mg
2+
, Ca
2+
, Ba
2+
, Cu
2+
, Zn
2+
, Cd
2+
, Pb
2+
,
, Mn
2+
, Fe
2+
, Co
2+
, Ni
2+
; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the individual extraction constants of the M
2+
cations in the mentioned two-phase system were calculated; they were found to increase in the following cation order:
< Zn
2+
, Ni
2+
< Cu
2+
, Cd
2+
< Co
2+
< Mg
2+
< Ca
2+
< Mn
2+
, Fe
2+
< Sr
2+
< Pb
2+
< Ba
2+
. From extraction experiments and [gamma]-activity measurements, the exchange extraction constants corresponding to the general equilibrium [M.sup.2+](aq) + [Sr.sup.2+](nb) [??] [+ or -] [M.sup.2+](nb) + [Sr.sup.2+](aq) taking part in the two-phase water-nitrobenzene system ([M.sup.2+] = [Mg.sup.2+], [Ca.sup.2+], [Ba.sup.2+], [Cu.sup.2+], [Zn.sup.2+], [Cd.sup.2+], [Pb.sup.2+],U[O.sup.2+.sub.2], [Mn.sup.2+], [Fe.sup.2+], [Co.sup.2+], [Ni.sup.2+]; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the individual extraction constants of the [M.sup.2+] cations in the mentioned two-phase system were calculated; they were found to increase in the following cation order: U[O.sup.2+.sub.2] < [Zn.sup.2+], [Ni.sup.2+] < [Cu.sup.2+], [Cd.sup.2+] < [Co.sup.2+] < [Mg.sup.2+] < [Ca.sup.2+] < [Mn.sup.2+], [Fe.sup.2+] < [Sr.sup.2+] < [Pb.sup.2+] < [Ba.sup.2+]. Keywords Dicarbollylcobaltate * Water-nitrobenzene system * Divalent metal cations * Individual extraction constants From extraction experiments and Delta *g-activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+(aq) + Sr2+(nb) [rlarr2] M2+(nb) + Sr2+(aq) taking part in the two-phase water--nitrobenzene system (M2+ = Mg2+, Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, \textUO22 + UO22+, Mn2+, Fe2+, Co2+, Ni2+; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the individual extraction constants of the M2+ cations in the mentioned two-phase system were calculated; they were found to increase in the following cation order: \textUO22 + UO22+ < Zn2+, Ni2+ < Cu2+, Cd2+ < Co2+ < Mg2+ < Ca2+ < Mn2+, Fe2+ < Sr2+ < Pb2+ < Ba2+. |
| Audience | Academic |
| Author | Vaňura, P. Makrlík, E. |
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| Copyright | Akadémiai Kiadó, Budapest, Hungary 2010 COPYRIGHT 2010 Springer |
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| Keywords | Water–nitrobenzene system Individual extraction constants Dicarbollylcobaltate Divalent metal cations |
| Language | English |
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| PublicationSubtitle | An International Journal Dealing with All Aspects and Applications of Nuclear Chemistry |
| PublicationTitle | Journal of radioanalytical and nuclear chemistry |
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| Snippet | From extraction experiments and
γ
-activity measurements, the exchange extraction constants corresponding to the general equilibrium M
2+
(aq) + Sr
2+
(nb) ⇄ M... From extraction experiments and [gamma]-activity measurements, the exchange extraction constants corresponding to the general equilibrium [M.sup.2+](aq) +... From extraction experiments and Delta *g-activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+(aq) + Sr2+(nb)... |
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| SubjectTerms | Cations Chemistry Chemistry and Materials Science Constants Diagnostic Radiology Extraction Hadrons Heavy Ions Inorganic Chemistry Mathematical analysis Nitrobenzenes Nuclear Chemistry Nuclear Physics Physical Chemistry Water Zinc compounds |
| Title | Individual extraction constants of some divalent metal cations in the two-phase water–nitrobenzene system |
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