Individual extraction constants of some divalent metal cations in the two-phase water–nitrobenzene system

From extraction experiments and γ -activity measurements, the exchange extraction constants corresponding to the general equilibrium M 2+ (aq) + Sr 2+ (nb) ⇄ M 2+ (nb) + Sr 2+ (aq) taking part in the two-phase water–nitrobenzene system (M 2+  = Mg 2+ , Ca 2+ , Ba 2+ , Cu 2+ , Zn 2+ , Cd 2+ , Pb 2+ ,...

Full description

Saved in:
Bibliographic Details
Published inJournal of radioanalytical and nuclear chemistry Vol. 285; no. 3; pp. 683 - 686
Main Authors Makrlik, E, Vanura, P
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 01.09.2010
Springer
Subjects
Cations
Chemistry
Chemistry and Materials Science
Constants
Diagnostic Radiology
Extraction
Hadrons
Heavy Ions
Inorganic Chemistry
Mathematical analysis
Nitrobenzenes
Nuclear Chemistry
Nuclear Physics
Physical Chemistry
Water
Zinc compounds
Water–nitrobenzene system
Individual extraction constants
Dicarbollylcobaltate
Divalent metal cations
Online AccessGet full text

Cover

More Information
Summary:From extraction experiments and γ -activity measurements, the exchange extraction constants corresponding to the general equilibrium M 2+ (aq) + Sr 2+ (nb) ⇄ M 2+ (nb) + Sr 2+ (aq) taking part in the two-phase water–nitrobenzene system (M 2+  = Mg 2+ , Ca 2+ , Ba 2+ , Cu 2+ , Zn 2+ , Cd 2+ , Pb 2+ , , Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ ; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the individual extraction constants of the M 2+ cations in the mentioned two-phase system were calculated; they were found to increase in the following cation order:  < Zn 2+ , Ni 2+  < Cu 2+ , Cd 2+  < Co 2+  < Mg 2+  < Ca 2+  < Mn 2+ , Fe 2+  < Sr 2+  < Pb 2+  < Ba 2+ .
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-010-0598-1