Performance analysis of a high-temperature magnesium hydride reactor tank with a helical coil heat exchanger for thermal storage

• Published in: International journal of hydrogen energy Vol. 46; no. 1; pp. 1038 - 1055
• Main Authors: Mathew, Arun, Nadim, Nima, Chandratilleke, Tilak T., Humphries, Terry D., Paskevicius, Mark, Buckley, Craig E.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.01.2021
• Subjects: Helical coil heat exchanger; Hydrogen storage; Magnesium hydride; Numerical modelling; Helical coil heat exchanger; Hydrogen storage; Magnesium hydride; Numerical modelling
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2020.09.191

Metal hydrides are regarded as one of the most attractive options for thermal energy storage (TES) materials for concentrated solar thermal applications. Improved thermal performance of such systems is vitally determined by the effectiveness of heat exchange between the metal hydride and the heat transfer fluid (HTF). This paper presents a numerical study supported by experimental validation on a magnesium hydride reactor fitted with a helical coil heat exchanger for enhanced thermal performance. The model incorporates hydrogen absorption kinetics of ball-milled magnesium hydride, with titanium boride and expanded natural graphite additives obtained by Sievert's apparatus measurements and considers thermal diffusion within the reactor to the heat transfer fluid for a realistic representation of its operation. A detailed parametric analysis is carried out, and the outcomes are discussed, examining the ramifications of hydrogen supply pressure and its flow rate. The study identifies that the enhancement of thermal conductivity in magnesium hydride has an insignificant impact on current reactor performance. •3-D validation of MgH2 reactor with a helical coil heat exchanger was performed.•Reaction kinetics was found out by using Sievert's apparatus.•Effect of operating parameters on MH reactor performance was studied.•Addition of 20% ENG into MH reactor, under the study, proved ineffective.