Solvent extraction of europium and americium into phenyltrifluoromethyl sulfone by using synergistic mixture of hydrogen dicarbollylcobaltate and “classical” CMPO

• Published in: Journal of radioanalytical and nuclear chemistry Vol. 283; no. 3; pp. 571 - 575
• Main Authors: Makrlik, E, Vanura, P, Selucky, P
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 01.03.2010; Springer
• Subjects: Americium; Cationic; Chemistry; Chemistry and Materials Science; Cytokinins; Diagnostic Radiology; Europium; Hadrons; Heavy Ions; Hydrogen; Inorganic Chemistry; Nuclear Chemistry; Nuclear Physics; Phosphine oxide; Physical Chemistry; Rare earth metals; Solvent extraction; Stability constants; Sulfones; CMPO; Extraction; Americium; Dicarbollylcobaltate; Europium; Phenyltrifluoromethyl sulfone; Complexes
• ISSN: 0236-5731; 1588-2780
• DOI: 10.1007/s10967-009-0379-x

Extraction of microamounts of europium and americium by a phenyltrifluoromethyl sulfone (FS 13) solution of hydrogen dicarbollylcobaltate (H + B − ) in the presence of octyl-phenyl- N,N -diisobutylcarbamoylmethyl phosphine oxide (“classical” CMPO, L) has been investigated. The equilibrium data have been explained assuming that the complexes , , , and (M 3+  = Eu 3+ , Am 3+ ) are extracted into the organic phase. The values of extraction and stability constants of the cationic complex species in FS 13 saturated with water have been determined. It was found that the stability constants of the corresponding complexes and , where n  = 2, 3, 4 and L is “classical” CMPO, in water-saturated FS 13 are comparable.