Structural studies of Nd1.85Ce0.15CuO4 + Ag superconducting system

• Published in: Bulletin of materials science Vol. 39; no. 3; pp. 627 - 632
• Main Authors: RAVEENDRAN, N RADHIKESH, SINHA, A K, RAJARAMAN, R, PREMILA, M, AMALADASS, E P, VINOD, K, JANAKI, J, KALAVATHI, S, MANI, AWADHESH
• Format: Journal Article
• Language: English
• Published: Bangalore, India Indian Academy of Sciences 01.06.2016; Springer Nature B.V
• Subjects: Bleaching; Chemistry and Materials Science; Crystal defects; Crystal structure; Engineering; Geometry; High temperature superconductors; Lattice vibration; Materials Science; Preferred orientation; Raman spectroscopy; Silver; Software; Spectrum analysis; Superconductivity; Synchrotron radiation; Synchrotrons; Unit cell; X-ray diffraction; structural studies; Raman spectroscopy; Cuprate superconductors
• ISSN: 0250-4707; 0973-7669
• DOI: 10.1007/s12034-016-1210-2

We have studied for the first time the effect of Ag addition (0–15 wt%) to the superconducting system, Nd 1.85 Ce 0.15 CuO 4 , on its crystal structure and local structural features, using synchrotron X-ray diffraction (SXRD) and Raman spectroscopy, respectively. SXRD and subsequent Rietveld refinement studies on powders of Nd 1.85 Ce 0.15 CuO 4 + Ag system indicate a small but significant change in lattice parameter upon Ag addition, showing evidence for possible incorporation of Ag to the extent of ∼ 1 wt%. Raman spectroscopic studies indicate that the parent structure of Nd 1.85 Ce 0.15 CuO 4 remains unaffected with no major local structural changes on doping with silver. However, all Raman modes show minor phonon hardening upon Ag addition, which is consistent with the unit cell volume reduction as is observed in XRD. A systematic bleaching out of the apical oxygen defect mode was also observed with increased Ag addition. Polarized Raman measurements helped to identify the asymmetric nature of the B 1g Raman mode. X-ray diffraction studies on pellets of Nd 1.85 Ce 0.15 CuO 4 + Ag system further indicate a randomization of preferred orientation upon Ag addition. The superconductivity of the Nd 1.85 Ce 0.15 CuO 4 + Ag system has been well characterized for all the compositions studied.