Novel iridium-pentafluorophenyl porphyrin complex

•A novel iridium porphyrin was synthesized.•It is proposed the stabilization of the porphyrin sphere with axial ligands.•Confirmation of iridium complex stability by spectroscopic techniques. The novel iridium-pentafluorophenyl porphyrin complex (TPFPPIrCl(CO)) was successfully synthesized by chemic...

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Bibliographic Details
Published inMaterials letters Vol. 200; pp. 6 - 9
Main Authors Delgado-Lima, Ana, Fonseca, António M., Machado, Ana V.
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.08.2017
Elsevier BV
Subjects
Chemical reactions
Chemical synthesis
Coordination chemistry
Iridium
Ligands
Mass spectrometry
Materials science
NMR spectroscopy
Porphyrins
Spectroscopy
Synthesis
Spectroscopy
Synthesis
Iridium
Coordination chemistry
Porphyrins
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Summary:•A novel iridium porphyrin was synthesized.•It is proposed the stabilization of the porphyrin sphere with axial ligands.•Confirmation of iridium complex stability by spectroscopic techniques. The novel iridium-pentafluorophenyl porphyrin complex (TPFPPIrCl(CO)) was successfully synthesized by chemical reaction with the iridium (I) metal precursor [Ir(COD)Cl]2. The final complex was identified linked to the axial Cl and CO ligands by UV–Visible, 1H, 13C NMR spectroscopy as well the 1H/13C correlated techniques and by mass spectrometry.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2017.03.177