Study the Thermal Stability of Nitrogen Doped Reduced Graphite Oxide Supported Copper Catalyst

• Published in: Journal of cluster science Vol. 29; no. 4; pp. 709 - 718
• Main Authors: Mageed, Alyaa K., Dayang Radiah, A. B., Salmiaton, A., Izhar, Shamsul, Razak, Musab Abdul
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.07.2018; Springer Nature B.V
• Subjects: Ammonia; Catalysis; Catalysts; Chemical reactions; Chemistry; Chemistry and Materials Science; Copper; Graphene; Graphite; Inorganic Chemistry; Metals; Methods; Morphology; Nanochemistry; Nitrogen; Original Paper; Oxidation; Physical Chemistry; Software; Thermal stability; Thermodynamic properties; Thermogravimetric analysis; X ray photoelectron spectroscopy; Nitrogen-doped reduced graphite oxide; Flynn–Wall–Ozawa model; Kissinger model; Copper catalyst; Thermogravimetric analysis
• ISSN: 1040-7278; 1572-8862
• DOI: 10.1007/s10876-018-1382-6

The thermal stability of the as-synthesized Nitrogen-doped reduced graphite oxide supported copper catalyst was investigated by a thermogravimetric analyzer (TGA) at a temperature range 273–1173 K under purified N 2 atmosphere using three different heating rates (15, 20 and 25 K min −1 ). Firstly, to obtained nitrogen-doped reduced graphite oxide (N-rGO), the functionalized graphite oxide was synthesized using Staudenmaier’s method reduced by continuously stirring in an ammonia solution subsequently. The rGO was doped with nitrogen and impregnated with Cu-precursor to obtain Cu/N-rGO. The as-synthesized GO; N-rGO and Cu/N-rGO were characterized by FESEM, EDX, TEM, XRD and XPS. All these analyses were resulted in successfully samples synthesized. The TGA kinetic data were fitted into Kissinger and Flynn–Wall–Ozawa model free expressions to obtain apparent activation energies of 83.34 and 102.59 J mol −1 and pre-exponential factors of 2.40 × 10 7 and 5.01 × 10 11  s −1 . The high R 2 values of 0.9999 and 0.9666 obtained from fitting TGA kinetic data using the Kissinger and Flynn–Wall–Ozawa model free expressions show that the data were well fitted to the expressions. This implies that the thermal behavior of nitrogen doped reduced graphite oxide supported Cu catalyst can be investigated using Kissinger and Flynn–Wall–Ozawa model free expressions.