Palladium nanoparticle microemulsions: Formation and use in catalytic hydrogenation of o-chloronitrobenzene
The formation and catalytic properties of well-dispersed palladium (Pd) nanoparticles in water-in-oil (w/o) microemulsions containing octadecyl amine polyoxyethylene ether (OAPE-5) and hydrogenated tallow amine (HTA) have been investigated. The size and structure of the nanoparticles were characteri...
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Published in | Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 165; no. 2; pp. 709 - 713 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Oxford
Elsevier B.V
01.12.2010
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | The formation and catalytic properties of well-dispersed palladium (Pd) nanoparticles in water-in-oil (w/o) microemulsions containing octadecyl amine polyoxyethylene ether (OAPE-5) and hydrogenated tallow amine (HTA) have been investigated. The size and structure of the nanoparticles were characterized by TEM and XRD analyses and the effects of microemulsion composition on particle sizes were assessed using FTIR spectroscopy. The results of TEM and XRD indicated that the particles were of a face centered cubic structure form and their mean diameter was 10
nm. Results of FTIR analysis indicated strong interactions between Pd nanoparticles and surfactant molecules. Use of these Pd nanoparticles for the hydrogenation of
o-chloronitrobenzene in the presence of alkali produced a 3:1 ratio of aniline to
o-chloroaniline and none of the frequently observed nitrobenzene or 2,2′-dichlorohydrazoebenzene. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 1385-8947 1873-3212 |
DOI: | 10.1016/j.cej.2010.10.022 |